Long-term freshwater quality monitoring data for Rainy River / Lake of the Woods Watershed for the past 15 years or longer for nutrients, metals, major ions, and other physical-chemical variables are included in this dataset. Monitoring is conducted by Environment and Climate Change Canada (ECCC) to assess water quality status and long-term trends, detect emerging issues, establish water quality guidelines and track the effectiveness of remedial measures and regulatory decisions. The information informs and supports the Fresh Water Action Plan.

Information received in response to notices published in the Canada Gazette under section 71 of the Canadian Environmental Protection Act (CEPA 1999). These notices target chemical substances of interest under the Chemicals Management Plan.

Wild fish community data (species, abundance, diversity, length, weight) for 2013 and 2019 are now available for tributaries of the Athabasca River (rivers Steepbank, Ells, Firebag, High Hills, Dunkirk, Horse, Muskeg, Tar and Calumet) and 2017 data for rivers and creeks adjacent to Christina Lake (Christina River, Sunday Creek, Birch Creek, Sawbones Creek, Jackfish Creek and Unnamed Creek). The composition and diversity of the fish communities in these waterbodies have been evaluated over time to identify changes in the presence and abundance of fish species in these waterbodies adjacent to SAGD oil sands mining activity and at sites that are outside of the Athabasca Oil Sands deposit and not influenced by mining activities. Not all waterbodies are adjacent to mining activities and these provide some information as to the natural variability and stability of these fish communities over time. This involved establishing baseline conditions in fish communities in the fall of 2013, 2017 and 2019. This baseline data has assisted in tracking changes in fish communities of these waterbodies over time. Fish community assessments (non-lethal sampling) were carried out in a reach of river using a Smith-Root 12B backpack, Smith-Root LR-24 backpack and or seine at the sites identified in Section 2.3. Length, weight, species identification, and external assessment were performed on fish collected. Fish were then returned to the water at the site of capture. This fish community assessment work commenced September 17th to 27th, 2013, October 3rd to 8th, 2017 and September 24th to October 2nd, 2019. This monitoring activity compliments and supports the Wild Fish Health program.

Wild fish health data (length, weight, gonad size, etc.) are now available for trout perch collected from the Athabasca and Peace Rivers; white sucker collected from the Athabasca River; longnose sucker collected from the Peace River; slimy sculpin collected from the Steepbank River; lake chub from Alice Creek, the Ells and Dover Rivers; and longnose dace from the Mackay River. Contaminants data available for walleye collected from the Athabasca and Peace Rivers. For each of these data sets, upstream reference areas are provided for comparison to downstream developed sites. Reference data are currently being evaluated for variability between years to develop triggers, and these triggers are essential to eventually quantify potential effects at exposed sites. Using existing critical effect sizes developed in the Environmental Effects Monitoring programs for pulp and paper and metal mining effluents, condition endpoints in white sucker were increased within the deposit. Slimy sculpin condition and reproductive endpoints are also exceeding effect sizes downstream of development sites. This data is now being used to predict future fish health endpoints within sites, between sites and relative to reference variability to help assess change in fish health.

Water level and discharge data are available from Water Survey of Canada’s Hydrometric Network. The Water Survey of Canada (WSC) is the national authority responsible for the collection, interpretation and dissemination of standardized water resource data and information in Canada. In partnership with the provinces, territories and other agencies, WSC operates over 2500 active hydrometric gauges across the country, maintains an archive of historical information for over 7600 stations and provides access to near real-time (water level and stream flow) provisional data at over 1700 locations in Canada.

Water Quality Monitoring on Tributaries in the Athabasca River Oil Sands Region Ells River (EL1, ELLS RIFF 2, ELLS RIFF5 [2012-2015]) Mackay River (MA1 [2012-2015], MA2 [2013-2015]) Steepbank River (STB RIFF1, STB WSC, STB RIFF7, STB RIFF10 [2012-2015]) Firebag River (FI1, FI WSC [2012-2015]) Muskeg River (MU1 [2012-2015]), MU6 [2012-2015]), MU7 [2012]) High Hills River (HIHI1 [2013-2015]) Water quality of tributaries in the Athabasca River oil sands region is heavily influenced by the presence of the underlying Cretaceous bedrock, which is comprised of shale, sandstone and limestone. The waters are moderately hard (average alkalinity of 114 mg l-1 CaCO3) because of their mineral content, particularly magnesium (average 8.62 mg l-1), calcium (average 28.06 mg l-1) and bicarbonate (138.53 mg l-1). This mineral content results in an average conductivity of 245 +/- 4 µS cm-1 and total dissolved solids concentration of 140 +/- 2 ppm. Concentrations of nitrogen and phosphorus (indicators of nutrient status) are typically low to moderate, averaging 0.14 mg l-1 total phosphorus, 0.03 mg l-1 total dissolved phosphorus, 0.92 mg l-1 total nitrogen, 0.09 mg l-1 nitrogen as nitrate+nitrite, and 0.04 mg l-1 nitrogen as total ammonia. Seasonal variation for the majority of water quality constituents within the Athabasca tributaries can be strong and is highly reflective of hydrological discharge (i.e., highest concentrations typically occur during snowmelt periods, especially for parameters that are bound to particulate matter). Spatial variation of parameters within tributaries general showed an increasing trend from upstream of development to samples collected downstream of development (near mouth of a tributary). Of the 45 water quality constituents (physical characteristics, major ions, metals, metalloids, selenium) and 52 Polycyclic Aromatic Compounds (PACs) analyzed, 28 have Guidelines for the Protection of Aquatic Life (Canadian Council of Ministers of the Environment – CCME). Only a few parameters were classified with frequent exceedances (i.e., >10% of of the approximately 1430 samples): total iron, 99% of all samples; total aluminum, 61%; total suspended solids, 39%; and total copper, 17%. All measurements of total mercury were below the CCME guideline; only pyrene from the PACs showed occasional exceedances (2% of samples) for established guidelines. Exceedances of guidelines are not uncommon in many river systems within and outside of the Oil Sands region and, in general, are associated with high flow events when suspended solids and contaminant loads are the greatest. High concentrations of suspended sediment (measured as total suspended solids) were observed during high flow events, such as occur during snowmelt and summer rainfall events. The high percentage of exceedances for iron was expected as these waters are known to have naturally-occurring high concentrations of iron. Mercury in Tributaries This data set includes river water concentrations of total mercury (THg; all forms of mercury in a sample) and methyl mercury (MeHg; the form of mercury that bioaccumulates through food webs) in five Athabasca River tributaries (Ells, Steepbank, Firebag, Muskeg and MacKay rivers). No samples exceeded the Canadian Council of Ministers of the Environment guidelines for THg and MeHg.

Sediment from Lakes Polycyclic aromatic hydrocarbons (PAHs), 47 elements including numerous metals, and visible reflectance spectroscopy or VRS-chla have been determined in sediment core samples collected in 2012, 2013 and 2014 from 16 small (surface area 4-97 ha; maximum depth ~1-5 m deep), hydrologically simple lakes located 30 to 120 km from major oil sands development areas. Canadian Council of Ministers of the Environment (CCME) guidelines are available for 13 of the 53 PAHs reported here. Sediment concentrations did not exceed Canadian Council of Ministers of the Environment (CCME) probable effects levels (PELs), which define the level above which biological adverse effects are expected to occur, for PAHs in any lake. Exceedances of the CCME interim sediment quality guidelines (ISQG) for the protection of aquatic life occurred for 4 PAHs (naphthalene, 2-methyl naphthalene phenanthrene, and benzo(a)pyrene) in 8 lakes. CCME sediment quality guidelines are available for 7 of the 47 elements reported here. Exceedances of the CCME ISQG for metals were found for arsenic in 3 lakes, cadmium in 8 lakes, mercury in 3 lakes and zinc in 9 lakes. Exceedances of the CCME PELs for metals occurred in 2 lakes for arsenic and 1 lake for zinc. Further assessment of the data is ongoing to examine reasons for exceedances as well as spatial and temporal trends of the PACs and elements. Analyses of lake primary productivity, using visible reflectance spectroscopy or VRS-chla as a proxy, show consistently greater productivity (i.e. VRS-chla concentrations) in the top sediment core slices relative to the bottom, regardless of lake morphological and limnological characteristics and landscape position. Potential drivers of these changes are being examined.

Acid-Sensitive Lakes Nine hundred and thirty-three lakes located in Saskatchewan, Alberta and the Northwest Territories were sampled to establish current acidification status. Of the 933 lakes, 244 (or 26%) are considered acid sensitive, almost always because of naturally low calcium and magnesium (or "base cation") concentrations. The most acid-sensitive lakes (i.e., those with extremely low base cation concentrations) are located on the Canadian Shield in both Alberta and Saskatchewan and east of the oils sands development area. Fifty-one of the 244 acid-sensitive lakes were sampled twice annually (spring and fall) to identify chemical changes through trend analyses. Results revealed that 55% of these lakes had concentrations of some metals in excess of Canadian Council of Ministers of the Environment guidelines. Of the 291 samples taken in the 51 lakes, iron concentrations were greater than guidelines in 36% (105 samples), aluminum in 33% (97 samples), lead in 0.3% (1 sample) and copper in 0.3% (1 sample). The metals in these lakes occur naturally and are expected to be found in a wide range of concentrations given the geology and physiography of the Canadian Shield. It remains to establish the relationship between acid sensitivity, geology and high metal concentrations.

Oil Sands Sediment Exposures of Embryo-larval Fathead Minnows Dataset contains laboratory-studied fathead minnow egg and larval survival rates when exposed to sediments collected from 18 sites in the Athabasca watershed (2010-2014). A controlled laboratory study examined the impacts on fathead minnow eggs and larval development when exposed to collected sediments at concentrations of 1, 5 and/or 25 g/L. Sediments and water were renewed daily, and eggs were assessed as they hatched (in about 5 days), and as the larval fish grew to 8-9 days post hatch (dph), and 15-16 dph. The data in the file present the mean survival (and standard deviation). Two sediment sites caused decreased survival of fathead minnow fry: The Ells River lower site, and the Steepbank River Lower site. These data show that sediment from these sites can affect larval fish survival in the lab. The next steps are to compare these findings to the health data from wild fish collected from these same tributary sites. Toxicity Testing of Groundwater near the Oil Sands Development Dataset contains toxicity studies of groundwaters collected near the Athabasca and Ells rivers. Groundwaters were collected in the summer of 2013 from 4 sites below the riverbeds at depths of 0.5 to 1 metre. Sites were chosen to represent groundwaters close to oil sands tailings ponds and further from tailings ponds and mining activities. Under controlled laboratory conditions, fathead minnow eggs were exposed for 5 days (until hatch) to the groundwaters at standard dilution concentrations of 6, 12, 25, 50, and 100% of the groundwater sample to compare egg and larval fish survival. The data presents the average survival until hatch of 3 repeated exposures (and standard deviation) and 9 repeated exposures for controls. Some groundwater is toxic to minnows and some is not. No correlations were found between toxicity and proximity to a tailings pond. Assessing Toxicity of Oil Sands Related Substances Laboratory fish were exposed to melted snow from sites located close to oil sands mining and upgrading facilities and from sites far away from mining activities to assess the toxicity of substances found in the snow. In addition, river waters, bed sediments, suspended sediments, groundwater and atmospheric depositional samples (pre-melt snow collections) were also tested for toxicity. Fish exposed to undiluted snowmelt showed biological effects. Fish exposed to river water from the region collected during snowmelt conditions showed no effects.

The objectives of the fish component of the integrated oil sands monitoring program are to provide the necessary data/information to address key questions related to both environmental health of fish populations and fish health issues that can be used to inform human use and consumption. The questions underlying the fish monitoring design are related to the status and health of wild fish populations in the Lower Athabasca River including and in an expanded geographical extent. Data is being collected to provide a baseline against which future changes in fish populations will be evaluated, and compared to data from historical studies to assess change over time to the current state. Data is also being collected in areas of new oil sands development, to develop baseline data for future site-specific comparisons, contribute to an expanded geographic basis of the overall monitoring plan, and contribute to an improved ability to examine cumulative effects.